Apr 25, 2019 · Due to -I effect of CN group, NC-CH 2 NH 2 is less basic than CH 3 NH 2. Further C 6 H 5 NHCH 3 is less basic than both CH 3 NH 2 and (CH 3 ) 2 NH due to delocalization of lone pair of electrons present on the nitrogen atom into benzene ring.
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  • CN Cl CN O O (Scheme 1) Stability It is known that DDQ reacts with water (Scheme 2) : hydrolysis of the cyanid-ion may occur after SN2mechanism, giving a deep-red colour ammonium salt in solution. O O Cl CN Cl CN H2O Cl O-, NH4+ Cl CN O O (Scheme 2) Stability is generally increased in acidic conditions, and at low temperatures.
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